The finalist of the previous Champions League Liverpool started their new season in Europe with a 1-4 away defeat in a game with Napoli.

2022-23, Champions League

Napoli - Liverpool 4:1 (3:0)
Goals: Zielinski P., 5 (penalty) (1:0); Zambo Anguissa André-Frank, 31 (2:0); Simeone, 44 (3:0); Zielinski P., 47 (4:0); Luis Díaz, 49 (4:1)

Napoli: Meret; Di Lorenzo; Kim Min-jae; Olivera M. (Mario Rui, 74); Rrahmani; Kvaratskhelia (Zerbin, 57); Lobotka; Zielinski P. (Elmas, 74); Politano (Lozano, 57); Zambo Anguissa André-Frank; Osimhen (Simeone, 41)
Bench: Sirigu; Skiri Ostigard; Juan Jesus; Zanoli; Gaetano G.; Ndombélé; Raspadori
Yellow Cards: Rrahmani 66

Liverpool: Alisson; Robertson A.; Fabinho; Gomez (Matip, 46); van Dijk; Milner (Alcantara T., 63); Alexander-Arnold; Firmino (Núñez D., 62); Elliott H. (Arthur Melo, 77); Salah (Jota, 62); Luis Díaz
Bench: Davies H.; Adrian; Phillips N.; Bajcetic; Tsimikas
Yellow Cards: Milner 10; van Dijk 17